Case study of hydrogen sulfide release in the sulfate-rich sewage drop structure

Abstract

H2S is one of the principal odor gases released from sewer networks and understanding the rate of H2S release into sewer air space and ventilation to the atmosphere is crucial for preventing or minimizing odor and corrosion issues in sewer systems. TOXCHEM model was used to simulate the fate of H2S gas in roads for this study. The model was calibrated for the spring and summer seasons and validated for the remainder of the seasons. The predicted behavior showed good correlation to measurements on real samples following statistical analysis, with R2, R, and RMSE results between (0.93–0.97), (0.8–0.82), and (0.000438–0.000838), respectively. A sensitivity study was performed to assess the effect of various pH values, drop heights, tailwater depths, stream widths, and sewer ventilation rate levels. The results showed that the emissions concentrations for winter, spring, summer, and autumn reached 3500, 5044, 6425, and 4045 ppm respectively. All the emissions levels from this DS can be considered hazardous, and this was particularly evident during the summer months. This study has helped to clarify the fate and emission of hydrogen sulfide gas at the DS by simulation using a TOXCHEM model. HIGHLIGHTS The drop structure can substantially increase the emission of hydrogen sulfide from the liquid phase to the air phase.; Discussion of the most important factors that contribute to the emission of H2S gas in the drop structures.; Determination of the amount of hydrogen sulfide gas emission in the sulfate-rich wastewater.; The use of the TOXCHEM model to simulate the emission of hydrogen sulfide gas in the drop structure.;

Keywords

• drop structure
• hydrogen sulfide
• h2s emission
• stream width
• toxchem model