Novel magnetite/persulphate/ozone hybrid system for catalytic degradation/ozonation of sunset yellow dye from wastewater

Abstract

Food dyes with a diverse set of colorants stimulate appetite and enhance aesthetic charm of food on table but at the same time these dyes contaminate the aquatic and biological ecosystems due to their cytotoxic and carcinogenic potentials. Herein, we report magnetite catalyzed removal of sunset yellow dye from water through catalytic degradation and ozonation. The magnetite catalyst revealed about 83% catalytic degradation and 92% catalytic ozonation performance toward sunset yellow dye at 100 and 25 min, respectively. Furthermore, the persulphate/magnetite/O3 hybrid system revealed superior performance compared to the persulphate/magnetite under identical conditions. Kinetic studies revealed that the dye degradation data followed second-order kinetics, suggesting that the dye removal process is physicochemical in nature. This study further demonstrates that the persulfate/magnetite/O3 hybrid system can efficiently decompose sunset yellow dye in aqueous solution compared to the Fenton’s reagent and simple catalytic decomposition processes which is attributed to its unique structural features.

Keywords

• Catalysis
• degradation
• fenton
• kinetics
• ozonation
• persulphate