Influence of Austenitisation Time and Temperature on Grain Size and Martensite Start of 51CrV4 Spring Steel

Abstract

51CrV4 spring steel is a martensitic steel grade that is heat treated by quenching and tempering. Therefore, austenitisation is an important step that influences steel properties. The main goal of austenitisation is to obtain a single-phase austenite structure that will transform into martensite. We studied the influence of austenitisation parameters on grain growth and martensite transformation temperatures. The samples were quenched from different austenitisation temperatures (800–1040 °C) and were held for 5, 10 and 30 min. The martensite start transformation temperatures (MS) were determined from dilatometric curves, and the hardness was measured using the Vickers method. The microstructure of the samples and the size of the prior austenite grains were characterised using optical microscopy. The increase in the size of the prior austenite crystal grains increases the MS temperature. However, this trend is visible up to 960 °C, where the results start to deviate. High temperatures, 960 °C and above, cause both grain growth and increased carbide dissolution along with chemical homogenization of the steel. The added influence of strong solute diffusion caused a big deviation in the results. The stability of carbides during austenitisation were evaluated with scanning electron microscopy (SEM) and thermodynamic calculations of equilibrium phases using the Thermo-Calc program. MC-type vanadium carbides are stable up to 956 °C under equilibrium conditions, but the SEM results show that they were present in the microstructure even after annealing at 1040 °C. This means that crystal growth is slowed down, which is positive, and that the austenite contains less carbon, so the hardness is lower.

Keywords

• spring steel
• martensite
• grain growth
• martensite start
• dilatometry
• austenitisation