Acta Crystallographica Section E (Apr 2013)

catena-Poly[[[bis(4-pyridinealdoxime-κN1)zinc]-μ-benzene-1,4-dicarboxylato-κ2O1:O4] 4-pyridinealdoxime monosolvate]

  • Hitoshi Kumagai,
  • Satoshi Kawata,
  • Yoshiyuki Sakamoto

DOI
https://doi.org/10.1107/S1600536813006107
Journal volume & issue
Vol. 69, no. 4
pp. m216 – m216

Abstract

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In the title compound, {[Zn(C8H4O4)(C6H6N2O)2]·C6H6N2O}n, the ZnII ion exhibits a tetrahedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the ZnII ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H...O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridinealdoxime molecule is located; this molecule is linked by O—H...O and O—H...N hydrogen bonds to the zigzag chain.