Recovery of Uranium by Se-Derivatives of Amidoximes and Composites Based on Them

Abstract

An Se-derivative of amidoxime was synthesized for the first time as a result of the reaction of oxidative polycondensation of N’-hydroxy-1,2,5-oxadiazole-3-carboximidamide with SeO2: its elementary units are linked to each other due to the formation of strong diselenide bridges. The element composition of the material was established, and the structure of the elementary unit was suggested. The sorption-selective properties were evaluated, and it was found that the adsorbent can be used for the selective recovery of U (VI) from liquid media with a pH of 6–9. The effect of some anions and cations on the efficiency of recovery of U (VI) was estimated. Composite materials were fabricated, in which silica gel with a content of 35, 50, and 65 wt.% was used as a matrix to be applied in sorption columns. The maximum values of adsorption of U (VI) calculated using the Langmuir equation were 620–760 mg g−1 and 370 mg g−1 for the composite and non-composite adsorbents, respectively. The increase in the kinetic parameters of adsorption in comparison with those of the non-porous material was revealed, along with the increase in the specific surface area of the composite adsorbents. In particular, the maximum sorption capacity and the rate of absorption of uranium from the solution increased two-fold.

Keywords

• uranium
• amidoximes
• sorption
• 1,2,5-oxadiazoles
• selenium