Nature Communications (Feb 2017)

A metamorphic inorganic framework that can be switched between eight single-crystalline states

  • Caihong Zhan,
  • Jamie M. Cameron,
  • David Gabb,
  • Thomas Boyd,
  • Ross S. Winter,
  • Laia Vilà-Nadal,
  • Scott G. Mitchell,
  • Stefan Glatzel,
  • Joachim Breternitz,
  • Duncan H. Gregory,
  • De-Liang Long,
  • Andrew Macdonell,
  • Leroy Cronin

DOI
https://doi.org/10.1038/ncomms14185
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 7

Abstract

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Crystal engineering is a powerful process for assembling complex materials but tends to require organic building blocks, which can limit stability. Here, the authors use inorganic polyoxometalates to assemble an all-inorganic metamorphic framework that can be switched between eight distinct states.