Journal of Materials Research and Technology (Nov 2022)

Corrosion electrochemistry properties of thermally sprayed Zn–Cu–Ti coating in simulated ocean atmosphere

  • Weiyi Zhang,
  • Ti Zhang,
  • Zongxiu Zhu,
  • Xinfeng Wang,
  • Jiqiu Qi,
  • Ya Ni,
  • Qingkun Meng,
  • Yanwei Sui,
  • Fuxiang Wei,
  • Yaojian Ren,
  • Yanqing Wang,
  • Lei Zhu

Journal volume & issue
Vol. 21
pp. 3235 – 3247

Abstract

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The electrochemical behavior of thermally sprayed Zn–Cu–Ti coating corroded in 3.5 wt% NaCl neutral salt spray for different days was investigated by electrochemical measurements. Electrochemical investigation shows that pitting corrosion occurs on the coating. Sacrificial anode protection and corrosion product protection play a dominant role. Coating corrosion can be divided into five stages: dissolution of surface oxides, deposition of corrosion products, stable dissolution of the coating, formation and development of occluded cell corrosion, and accelerated corrosion stage. The degradation mechanism and the role of galvanic protection of coating have been discussed by a proposed corrosion model.

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