Preparation and luminescence properties of Tm3+-doped SrBi2Ta2O9 blue-emitting phosphor

Abstract

Various novel SrBi2Ta2O9:Tm3+ blue-emitting materials were achieved via solid-state synthesis. The structure and phase purity of prepared SrBi2Ta2O9:xTm3+ (x = 0.005-0.30 mol) were examined by X-ray powder diffraction. The surface morphology of SrBi2Ta2O9:0.01Tm3+ were studied by scanning electron microscopy. Photoluminescence properties were systematically explored under the monitoring emission (λem = 468 nm) and excitation (λex = 303 nm) spectra. The optimum mole ratio of as-synthesized phosphors was 0.01 mol. The concentration quenching mechanism in the SrBi2Ta2O9 host was due to electric multipole interaction. Particularly, the chromaticity coordinates (0.1334, 0.0474) of SrBi2Ta2O9:0.01Tm3+ are near to those of the commercial BaMgAl10O17:Eu2+. These results validated the SrBi2Ta2O9:Tm3+ phosphor can be utilized good blue-emitting candidate for W-LEDs.