Low-temperature synthesis, characterization and photocatalytic properties of lanthanum vanadate LaVO4

Abstract

In this study, we have successfully prepared tetragonal lanthanum vanadate LaVO4 nanoparticles by a facile co-precipitation method at room temperature. The obtained materials were characterized using different structural and micro-structural techniques such as the characterization by X-ray diffraction (XRD), UV–Vis diffuse reflectance spectrum (DRS), transmission electron microscopy (TEM), and Raman spectrometry. The obtained structure is crystallized in single tetragonal phase with pin-like nanostructure. A main optical transition with bandgap energy of 3.26 eV is evidenced, and the average lifetime of charges carriers was found to be 1 ns Furthermore, the photoluminescence occurs in the visible light range. The photocatalytic activity was evaluated by the photocatalytic degradation of methylene blue (MB) with initial concentration of 10 mg L−1. The result indicates that LaVO4 particles showed a best photocatalytic activity of 98.2% degradation for methylene blue solution after irradiation of 90 min under visible light. Furthermore, the photocatalytic mechanism and reusability were studied.

Keywords

• Lanthanum vanadate
• Photocatalysis
• Dye degradation
• Optical properties