Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides

Franz A. Mautner; Roland C. Fischer; Bailey R. Williams; Salah S. Massoud; Nahed M. H. Salem

doi:10.3390/cryst10040317

Crystals (Apr 2020)

Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides

Franz A. Mautner,
Roland C. Fischer,
Bailey R. Williams,
Salah S. Massoud,
Nahed M. H. Salem

Affiliations

Franz A. Mautner: Institut für Physikalische and Theoretische Chemie, Technische Universität Graz, A-8010 Graz, Austria
Roland C. Fischer: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9/V, A-8010 Graz, Austria
Bailey R. Williams: Department of Chemistry, University of Louisiana at Lafayette, P.O. Box 43700 Lafayette, LA 70504, USA
Salah S. Massoud: Department of Chemistry, University of Louisiana at Lafayette, P.O. Box 43700 Lafayette, LA 70504, USA
Nahed M. H. Salem: Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 21511 Moharam Bey, Alexandria, Egypt

DOI: https://doi.org/10.3390/cryst10040317
Journal volume & issue: Vol. 10, no. 4
p. 317

Abstract

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A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd6(TPA)4(μ3-1,1,3-N3)4(μ2-1,1-N3)6](ClO4)2·2H2O (1) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N3 bridging modes.

Published in Crystals

ISSN: 2073-4352 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Crystallography
Website: http://www.mdpi.com/journal/crystals/

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