H2S removal by copper enriched porous carbon cuboids

Eleni Thomou; Georgia Basina; Konstantinos Spyrou; Yasser Al Wahedi; Petra Rudolf; Dimitrios Gournis

Carbon Trends (Apr 2022)

H2S removal by copper enriched porous carbon cuboids

Eleni Thomou,
Georgia Basina,
Konstantinos Spyrou,
Yasser Al Wahedi,
Petra Rudolf,
Dimitrios Gournis

Affiliations

Eleni Thomou: Department of Materials Science and Engineering, University of Ioannina, GR, 45110, Ioannina, Greece; Zernike Institute for Advanced Materials, University of Groningen, 9747 AG Groningen, The Netherlands
Georgia Basina: Department of Chemical Engineering, Khalifa University, Sas Al Nakhl Campus, P.O. Box 2533, Abu Dhabi, United Arab Emirates
Konstantinos Spyrou: Department of Materials Science and Engineering, University of Ioannina, GR, 45110, Ioannina, Greece
Yasser Al Wahedi: Department of Chemical Engineering, Khalifa University, Sas Al Nakhl Campus, P.O. Box 2533, Abu Dhabi, United Arab Emirates; Center for Catalysis and Separation, Khalifa University, P.O. Box 127788, Abu Dhabi, United Arab Emirates; Corresponding authors.
Petra Rudolf: Zernike Institute for Advanced Materials, University of Groningen, 9747 AG Groningen, The Netherlands; Corresponding authors.
Dimitrios Gournis: Department of Materials Science and Engineering, University of Ioannina, GR, 45110, Ioannina, Greece; Corresponding author at: Department of Materials Science and Engineering, University of Ioannina, Ioannina, GR 45110, Greece.

Journal volume & issue: Vol. 7
p. 100145

Abstract

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Hydrogen sulfide (H2S) removal by adsorption from gas streams is crucial to prevent the environmental and industrial damage it causes. Amongst the nanostructures considered excellent candidates as sorbents, porous carbon has been studied extensively over the last years. In the present work we present a synthetic procedure for three high potential sorbents based on carbon cuboids, namely a low-surface-area copper-rich structure, a highly porous aggregate without metal addition, and lastly the same porous carbon decorated with copper. The properties and performance as catalysts of these three sorbents were evaluated by powder X-ray diffraction, X-ray photoelectron spectroscopy, thermal analysis, scanning electron microscopy with energy dispersive X-ray analysis, surface area determination through N2 adsorption and desorption, as well as by H2S adsorption measurements.

Published in Carbon Trends

ISSN: 2667-0569 (Online)
Publisher: Elsevier
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry
Website: https://www.journals.elsevier.com/carbon-trends/

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