Origin of the colossal dielectric properties in double-perovskite Sr2CoNbO6

Abstract

Sr2CoNbO6 ceramics were prepared via the solid-state reaction route. The dielectric properties of Sr2CoNbO6 ceramics were investigated as a function of temperature (90–330 K) in the frequency range from 20 Hz to 10 MHz. Our results reveal that the dielectric properties of Sr2CoNbO6 are closely linked with the conductivity of the sample. The conductivity is dominated by hopping localized carriers. The hopping process not only produces considerable conductivity followed the universal dielectric response behavior, but also gives rise to dipolar effects leading to the polaron relaxation in intermediate-temperature range. At low enough temperatures, the hopping process is frozen-in and the low-temperature Maxwell-Wagner relaxation due to frozen carriers featuring the nearly constant loss behavior appears. At higher temperatures, the long-distance transportation of the carriers becomes remarkable. These carriers are easily blocked by various interfaces resulting in space charge therein and the conventional Maxwell-Wagner relaxation in the high-temperature range. Our results demonstrate that a multirelaxation mechanism instead of a single relaxation underlies the colossal dielectric properties of Sr2CoNbO6.