Nature Communications (Jan 2022)

On-surface synthesis and characterization of nitrogen-substituted undecacenes

  • Kristjan Eimre,
  • José I. Urgel,
  • Hironobu Hayashi,
  • Marco Di Giovannantonio,
  • Pascal Ruffieux,
  • Shizuka Sato,
  • Satoru Otomo,
  • Yee Seng Chan,
  • Naoki Aratani,
  • Daniele Passerone,
  • Oliver Gröning,
  • Hiroko Yamada,
  • Roman Fasel,
  • Carlo A. Pignedoli

DOI
https://doi.org/10.1038/s41467-022-27961-1
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 9

Abstract

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Heteroatom substitution in larger acenes represents a fundamental step towards precise engineering of the remarkable electronic properties of the acene family. Here, the authors present an on-surface synthesis strategy and detailed characterization for three undecacene analogs substituted with four nitrogen atoms.