Acta Crystallographica Section E (Jul 2009)

[Tris(3,5-diphenylpyrazolyl)hydroborato]nickel(II) bromide

  • David J. Harding,
  • Phimphaka Harding,
  • Harry Adams

DOI
https://doi.org/10.1107/S1600536809021606
Journal volume & issue
Vol. 65, no. 7
pp. m773 – m773

Abstract

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In the title tris(pyrazolyl)borate (TpPh2) complex, [NiBr(C45H34BN6)], the Ni, Br and B atoms lie on a crystallographic threefold axis and a distorted NiN3Br tetrahedral geometry arises for the metal ion. In the crystal, C—H...(C=C) and C—H...π interactions help to establish the polar crystal packing.