New Approaches in Electroanalytical Determination of Triazines-Based Pesticides in Natural Waters

Abstract

This study describes the preparation and use of a dental amalgam electrode for the voltammetric determination of triazine-based pesticides ametryn, atrazine, and simazine in natural waters, using square wave voltammetry. The experimental and voltammetric parameters were previously optimized, and analytical curves were constructed to calculate analytical parameters. The detection limits presented values that were lower than the maximum limits of residues permitted in natural water by the Brazilian Environmental Agency, 100 µg L−1 (100 ppb), and around the values obtained using other electrodic surfaces or high-performance liquid chromatography, traditionally used in triazine levels determination. Furthermore, the recovery percentages in pure electrolyte and natural waters were around 100%, demonstrating that the methodology proposed is suitable for determining triazines contamination in natural water samples, based on an environmentally friendly procedure.

Keywords

• triazine-based pesticides
• ametryn
• atrazine
• simazine
• dental amalgam electrode
• square wave voltammetry