Hydrothermal Carbonization of Waste Sugarcane Bagasse for the Effective Removal of Emerging Contaminants from Aqueous Solution

Abstract

Porous carbon spheres were fabricated from sugarcane bagasse using a sustainable hydrothermal carbonization process followed by alkali impregnation inert atmosphere activation. Developed spheres were technically analysed for their chemical science, structural morphology, texture, porosity with respect to size distribution, and thermal degradation. Spheres are functionally enriched with oxygenated groups showing amorphous nature portraying as a smooth surface. After activation, intensity of functional groups is reduced due to reduction reaction by KOH thereby yielding highly rich porous carbon. The active surface area developed on spheres is 111 m2 g-1 holding pores that are mesoporous in nature. Resistance to thermal exposure using TGA showed that decomposition of hemicelluloses followed by cellulose yielded aromatized carbon-rich skeleton through thermal degradation of carboxyl and hydroxyl groups. Developed carbon was found to be effective in removing Ciprofloxacin Hydrochloride from water with maximum adsorption capacity of 110.008 mg g-1. Mechanistic removal followed pseudo-second-order kinetics along with Freundlich mode of adsorption. The presence of carboxylic and hydroxyl groups in porous carbon favoured elimination of CPF from water. The development of HTC-derived carbon helped conserving the energy thereby reducing the cost requirement.