Bis(2,4-dioxopentan-3-ido-κ2O,O′)dioxidomolybdenum(VI): a redetermination

Abstract

The title compound, [Mo(C5H7O2)2O2] or cis-[MoO2(acac)2] (acac is acetylacetonate), contains a molybdenum(VI) atom coordinated by two acetylacetonate ligands and two doubly bonded oxido ligands in a distorted octahedral shape. The molecule is chiral and the asymmetric unit contains two independent molecules (one Δ, one Λ). Extensive C—H...O contacts are present throughout the structure. Data were collected at 100 K, providing higher precision of unit-cell parameters and atomic positions than previous determinations [Kamenar et al. (1973). Cryst. Struct. Commun. 2, 41–44.; Krasochka et al. (1975). Zh. Strukt. Khim. 16, 696–698].

Keywords

• crystal structure
• molybdenum
• oxo
• acetylacetonate
• acac