Network Structured CuWO₄/BiVO₄/Co-Pi Nanocomposite for Solar Water Splitting

Abstract

A network structured CuWO4/BiVO4 nanocomposite with a high specific surface area was prepared from CuWO4 nanoflake (NF) arrays via a method that combined drop-casting and thermal annealing. The obtained CuWO4/BiVO4 exhibited high catalytic activity toward photoelectrochemical (PEC) water oxidation. When cobalt phosphate (Co-Pi) was coupled with CuWO4/BiVO4, the activity of the resulting CuWO4/BiVO4/Co-Pi composite for the oxygen evolution reaction (OER) was further improved. The photocurrent density (Jph) for OER on CuWO4/BiVO4/Co-Pi is among the highest reported on a CuWO4-based photoanode in a neutral solution. The high activity for the PEC OER was attributed to the high specific surface area of the composite, the formation of a CuWO4/BiVO4 heterojunction that accelerated electron⁻hole separation, and the coupling of the Co-Pi co-catalyst with CuWO4/BiVO4, which improved the charge transfer rate across composite/solution interface.

Keywords

• photoelectrochemical water splitting
• oxygen evolution reaction
• copper tungstate
• bismuth vanadate
• cobalt phosphate