4-[(E)-(4-Fluorobenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione

Abstract

In the asymmetric unit of the title compound, C10H9FN4S, there are two independent molecules in which the dihedral angles between the 1,2,4-triazole and benzene rings are 36.85 (10) and 7.81 (10)°. In the crystal, N—H...S interactions link pairs of independent molecules into dimers. There are also π–π interactions between the triazole and benzene rings of inversion-related pairs of the more planar molecule [centroid–centroid distance = 3.6430 (13) Å].