N-(3-Chloropropionyl)-N′-phenylthiourea

Abstract

The title compound, C10H11ClN2OS, adopts a cis-trans configuration with respect to the position of the phenyl and 3-chloropropionyl groups relative to the thiono group across the C—N bonds. The benzene ring is perpendicular to the propionyl thiourea fragment with a dihedral angle of 82.62 (10)°. An intramolecular N—H...O interaction occurs. The crystal structure is stabilized by intermolecular N—H...S hydrogen bonds, which link pairs of molecules, building up R22(8) ring motifs, and C—H.. π interactions.