Integrated redox-active reagents for photoinduced regio- and stereoselective fluorocarboborylation

Weigang Zhang; Zhenlei Zou; Wenxuan Zhao; Shuo Lu; Zhengguang Wu; Mengjun Huang; Xiaochen Wang; Yi Wang; Yong Liang; Yi Zhu; Youxuan Zheng; Yi Pan

doi:10.1038/s41467-020-16477-1

Nature Communications (May 2020)

Integrated redox-active reagents for photoinduced regio- and stereoselective fluorocarboborylation

Weigang Zhang,
Zhenlei Zou,
Wenxuan Zhao,
Shuo Lu,
Zhengguang Wu,
Mengjun Huang,
Xiaochen Wang,
Yi Wang,
Yong Liang,
Yi Zhu,
Youxuan Zheng,
Yi Pan

Affiliations

Weigang Zhang: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Zhenlei Zou: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Wenxuan Zhao: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Shuo Lu: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Zhengguang Wu: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Mengjun Huang: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Xiaochen Wang: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Yi Wang: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Yong Liang: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Yi Zhu: Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University
Youxuan Zheng: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University
Yi Pan: State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University

DOI: https://doi.org/10.1038/s41467-020-16477-1
Journal volume & issue: Vol. 11, no. 1
pp. 1 – 7

Abstract

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The synthesis of vinylboronates and alkylboronates often suffers from step-tedious and poorly stereoselective procedures. Here, the authors report a bench-stable redox-active reagent for the radical difunctionalization of alkenes and alkynes affording fluorine-containing vinylboronates and alkylboronates.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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