Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

Kariska Potgieter; Frederick P. Malan; Oyekunle Azeez Alimi; Reinout Meijboom

doi:10.1107/S2414314622011476

IUCrData (Dec 2022)

Tris(benzyldiphenylphosphane-κP)(nitrato-κO)silver(I)

Kariska Potgieter,
Frederick P. Malan,
Oyekunle Azeez Alimi,
Reinout Meijboom

Affiliations

Kariska Potgieter: Department of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa
Frederick P. Malan: Department of Chemistry, University of Pretoria, Lynnwood Road, Hatfield, Pretoria, 0002, South Africa
Oyekunle Azeez Alimi: Department of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa
Reinout Meijboom: Department of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa

DOI: https://doi.org/10.1107/S2414314622011476
Journal volume & issue: Vol. 7, no. 12
p. x221147

Abstract

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The molecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetrahedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag—O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary interaction of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete molecule in the asymmetric unit. Weak C—H...O interactions consolidate the packing.

Published in IUCrData

ISSN: 2414-3146 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://iucrdata.iucr.org

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