Frontiers in Materials (Jan 2022)

Tailoring Ferrimagnetic Transition Temperatures, Coercivity Fields, and Saturation Magnetization by Modulating Mn Concentration in (CoCrFeNi)1−xMnx High-Entropy Alloys

  • Chi-Hung Lee,
  • Hsu-Hsuan Chin,
  • Kun-Yuan Zeng,
  • Yao-Jen Chang,
  • Yao-Jen Chang,
  • An-Chou Yeh,
  • An-Chou Yeh,
  • Jien-Wei Yeh,
  • Jien-Wei Yeh,
  • Su-Jien Lin,
  • Su-Jien Lin,
  • Chun-Chieh Wang,
  • Chun-Chieh Wang,
  • Uwe Glatzel,
  • E-Wen Huang,
  • E-Wen Huang

DOI
https://doi.org/10.3389/fmats.2022.824285
Journal volume & issue
Vol. 9

Abstract

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Cr and Mn play intriguing roles in determining the magnetic properties of CoFeNi-based high-entropy alloys (HEA). In this study, we tune the stoichiometric Mn composition to systematically explore the magnetic properties of (CoCrFeNi)1−xMnx HEAs. We observe a change from ferro-to ferrimagnetism due to the incorporation of Mn atoms into the CoCrFeNi HEA. In addition, we measure an 81% reduction in magnetization with the incorporation of 7.6 (2)% Mn atoms. Such a significant reduction in magnetization cannot be solely explained by the effect of the inversed moments on the Mn atoms. Hence, we propose a mechanism whereby the Mn atoms flip the moments of neighboring atoms, which results in the magnetization reduction observed in the CoFeNi-based HEAs.

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