Enhanced Thermal Stability in Dielectric Properties of NaNbO₃–Modified BaTiO₃–BiMg_1/2Ti_1/2O₃ Ceramics for X9R-MLCC Applications

Abstract

0.5BaTiO3–(0.5 − x)BiMg1/2Ti1/2O3–xNaNbO3 (x = 0.10–0.30) ceramics were processed via a conventional solid state sintering route. X-ray diffraction analysis and Raman spectroscopy showed the formation of a cubic perovskite structure. Microstructural analysis of the samples revealed densely packed grains. The addition of NaNbO3 resulted in the enhancement in dielectric properties as a function of temperature. Relative permittivity decreased from 850 to 564 (at room temperature) with an increase in x; however, the stability in dielectric properties was improved with an increase in NaNbO3 concentration. At x = 0.25, relative permittivity (εr) was ~630 ± 15% in a temperature range of −70–220 °C with low dielectric loss (tan δ) 3 which meet the criterion for X9R MLCC applications.

Keywords

• BaTiO₃
• capacitor
• dielectric properties
• X9R