catena-Poly[[[aqua[3-(3-hydroxyphenyl)prop-2-enoato]samarium(III)]-bis[μ2-3-(3-hydroxyphenyl)prop-2-enoato]] monohydrate]

Abstract

The title SmIII compound, {[Sm(C9H7O3)3(H2O)]·H2O}n, was obtained under hydrothermal conditions. Its structure is isotypic with the analogous Eu complex. The latter was reported incorrectly in space group P1 by Yan et al. [J. Mol. Struct. (2008), 891, 298–304]. This was corrected by Marsh [Acta Cryst. B65, 782–783] to P-1. The SmIII ion is nine-coordinated by O atoms from one coordinating water molecule and the remaining ones from the 3-(3-hydroxyphenyl)prop-2-enoatate anions (one bidentate, two bidentate and bridging, two monodentate bridging), leading to a distorted tricapped trigonal–prismatic coordination polyhedron surrounded by solvent water molecules. In the crystal, extensive intermolecular O—H...O hydrogen-bonding interactions and π–π interactions [centroid–centroid separation = 3.9393 (1) Å] lead to the formation of a three-dimensional supramolecular network.