Nature Communications (Dec 2019)

Unveiling how intramolecular stacking modes of covalently linked dimers dictate photoswitching properties

  • Ru-Qiang Lu,
  • Xiao-Yun Yan,
  • Lei Zhu,
  • Lin-Lin Yang,
  • Hang Qu,
  • Xin-Chang Wang,
  • Ming Luo,
  • Yu Wang,
  • Rui Chen,
  • Xiao-Ye Wang,
  • Yu Lan,
  • Jian Pei,
  • Wengui Weng,
  • Haiping Xia,
  • Xiao-Yu Cao

DOI
https://doi.org/10.1038/s41467-019-13428-3
Journal volume & issue
Vol. 10, no. 1
pp. 1 – 8

Abstract

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Covalently bridged π-stacked dimers are excellent molecular platforms for understanding the relationship between stacking orientation and properties. Here, the authors synthesize a pair of π-stacked dimers that are aligned either cofacially or crosswise, allowing them to compare how the intramolecular stacking mode affects each dimer’s photoswitching properties.