Acta Crystallographica Section E (Dec 2012)

Dimethylbis(2-methylquinolin-8-olato-κ2N,O)tin(IV)

  • Ezzatollah Najafi,
  • Mostafa M. Amini,
  • Seik Weng Ng

DOI
https://doi.org/10.1107/S1600536812047393
Journal volume & issue
Vol. 68, no. 12
pp. m1551 – m1551

Abstract

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The SnIV cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methylquinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the molecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyltin skeleton [C—Sn—C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak intermolecular C—H...O hydrogen bonding occurs in the crystal.