Nature Communications (Mar 2021)

Pressure-induced ferroelectric-like transition creates a polar metal in defect antiperovskites Hg3Te2X2 (X = Cl, Br)

  • Weizhao Cai,
  • Jiangang He,
  • Hao Li,
  • Rong Zhang,
  • Dongzhou Zhang,
  • Duck Young Chung,
  • Tushar Bhowmick,
  • Christopher Wolverton,
  • Mercouri G. Kanatzidis,
  • Shanti Deemyad

DOI
https://doi.org/10.1038/s41467-021-21836-7
Journal volume & issue
Vol. 12, no. 1
pp. 1 – 10

Abstract

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Generally, ferroelectricity in ABO3 perovskites is suppressed by hydrostatic compression, but the evidence for pressure-induced ferroelectricity remains elusive. Here, the authors find a direct ferroelectric-like structural transition induced by pressure in defect antiperovskites.