Acta Crystallographica Section E (Sep 2011)

Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ2O1,O2)cobaltate(II) dihydrate: an ion-pair complex

  • Papa Aly Gaye,
  • Adama Sy,
  • Ibrahima Elhadj Thiam,
  • Mohamed Gaye,
  • Pascal Retailleau

DOI
https://doi.org/10.1107/S1600536811031357
Journal volume & issue
Vol. 67, no. 9
pp. m1269 – m1269

Abstract

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The CoII ion in the title complex, (C4H14N2)2[Co(C2O4)3]·2H2O, is coordinated by three oxalate ions, resulting in a distorted octahedral geometry. Two uncoordinated water molecules are present in asymmetric unit. Intermolecular N—H...O and O—H...O hydrogen bonds between the different entities stabilize the crystal structure.