Corrosion of an AZ31B Magnesium Alloy by Sulfate-Reducing Prokaryotes in a Mudflat Environment

Abstract

To study the abnormal failure of magnesium anodes for buried pipelines in marine engineering in the unique environment of mudflats, a strain of a sulfate–reducing prokaryote (SRP) was isolated from pipe–laying soil, and identified as Desulfovibrio sp. HQM3. Weight–loss test, electrochemical measurements, SEM, EDS, XRD, and CLSM techniques were used to study the effect of corrosion on the AZ31B magnesium alloy. Under the influence of SRP, the magnesium alloy corroded severely at rates up to 1.31 mm/year in the mudflat environment. SRP accelerated corrosion by 0.3mm/year. Pitting occurred on the samples in both abiotic and biotic systems. The pitting depth reached 163.47 μm in the biotic system after 14 days. The main composition of a petal–like corrosion product was Mg(OH)2. The results show that a mudflat environment can lead to an accelerated corrosion of magnesium alloys.

Keywords

• sulfate–reducing prokaryotes
• mudflat environment
• magnesium alloy
• Microbiologically Influenced Corrosion
• electrochemical impedance spectroscopy