IUCrData (Nov 2022)

Bis(acetylacetonato-κ2O,O′)(N,N,N′,N′-tetramethylethylenediamine-κ2N,N′)magnesium(II)

  • Jan Henrik Halz,
  • Christian Heiser,
  • Kurt Merzweiler

DOI
https://doi.org/10.1107/S2414314622010355
Journal volume & issue
Vol. 7, no. 11
p. x221035

Abstract

Read online

The title complex, [Mg(C5H7O2)2(C6H16N2)], has been synthesized from magnesium acetylacetonate [Mg(acac)2] and tetramethylethylenediamine (TMEDA) in n-hexane. The monomeric complex consists of a central magnesium(II) atom, which is surrounded nearly octahedrally by two chelating acetylacetonato ligands and one chelating TMEDA ligand. [Mg(C5H7O2)2(C6H16N2)] is isotypic with its Zn analogue.

Keywords