Acta Crystallographica Section E (Dec 2009)

Di-μ-iodido-bis[acetyl(4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane)(N-nitroso-N-oxidoaniline-κ2O,O′)rhodium(III)]

  • H. G. Visser,
  • W. Purcell,
  • Johan A. Venter

DOI
https://doi.org/10.1107/S1600536809043050
Journal volume & issue
Vol. 65, no. 12
pp. m1528 – m1529

Abstract

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The title compound, [Rh2(C6H5N2O2)2(C2H3O)2I2(C5H9O3P)2], contains a binuclear centrosymmetric RhIII dimer bridged by iodide anions, with respective Rh...Rh and I...I distances of 4.1437 (5) and 3.9144 (5) Å. The RhIII atom is in a distorted octahedral RhCI2O2P coordination with considerably different Rh—I distances to the bridging iodide anions. There are no classical hydrogen-bonding interactions observed for this complex.