Innovative ionic liquid pretreatment followed by wet disk milling treatment provides enhanced properties of sugar palm nano-fibrillated cellulose

Abstract

In order to accommodate the increased demand for innovative materials, intensive research has focused on natural resources. In pursuit of advanced substances that exhibit functionality, sustainability, recyclability, and cost-effectiveness, the present work attempted an alternative study on cellulose nanofibers derived from sugar palm fiber. Leveraging an innovative approach involving ionic liquid (IL) pre-treatment, bleaching, and wet disc mill technique, nano-fibrillated cellulose (NFC) was successfully obtained from the sugar palm fiber source. Remarkably, 96.89% of nanofibers were extracted from the sugar palm fiber, demonstrating the process's efficacy and scalability. Further investigation revealed that the sugar palm nano-fibrillated cellulose (SPNFC) exhibited a surface area of 3.46 m2/g, indicating a significant interface for enhanced functionality. Additionally, the analysis unveiled an average pore size of 4.47 nm, affirming its suitability for various applications that necessitate precise filtration. Moreover, the surface charge densities of SPNFC were found to be −32.1 mV, offering opportunities for surface modification and enhanced interactions with various materials. The SPNFC exhibit remarkable thermal stability, enduring temperatures of up to 360.5 °C. Additionally, the isolation process is evident in a significant rise in the crystallinity index, escalating from 50.97% in raw fibers to 61.62% in SPNFC. These findings shed light on the vast potential and distinct features of SPNFC, opening the path for its application in a wide array of industries, including but not limited to advanced materials, biomedicine, and environmental engineering.

Keywords

• Sugar palm fiber
• Ionic liquid pretreatment
• Isolation
• Wet disk mill
• Cellulose nanofiber