Turing patterns in a 3D morpho-chemical bulk-surface reaction-diffusion system for battery modeling

Abstract

In this paper we introduce a bulk-surface reaction-diffusion (BS-RD) model in three space dimensions (3D) that extends the so-called DIB morphochemical model to account for the electrolyte contribution in the application, in order to study structure formation during discharge-charge processes in batteries. Here we propose to approximate the model by the bulk-surface virtual element method (BS-VEM) on a tailor-made mesh that proves to be competitive with fast bespoke methods for PDEs on Cartesian grids. We present a selection of numerical simulations that accurately match the classical morphologies found in experiments. Finally, we compare the Turing patterns obtained by the coupled 3D BS-RD model with those obtained with the original 2D version.

Keywords

• batteries
• metal electrode
• electrodeposition
• bulk-surface reaction-diffusion systems
• bulk-surface virtual element method
• turing patterns