Efeitos de agentes oxidantes e oxigênio dissolvido na descoloração do azo corante acid orange 7 por fotólise e fotocatálise Effects of oxidant agents and dissolved oxygen on the decolorization of acid orange 7 azo dye by photolysis and photocatalysis

Abstract

The decolorization of acid orange 7 azo dye by photolysis and photocatalysis by ZnO was investigated in the presence of oxidants such as NaClO3, NaBrO3, NaIO4, and K2S2O8 in an open reactor at 30 ºC. The decolorization was relatively fast at lower oxidants concentrations and slow rate at larger concentrations, except for persulfate in the photocatalysis. Concerning photolysis the rate constant enhanced gradually, except for chlorate, outreaching the obtained values by photocatalysis, at higher concentrations. The air saturation decreased the rate constant in both processes and indicated that the azo dye can be decolorized without dissolved oxygen in persulfate medium.

Keywords

• acid orange 7
• photolysis
• photocatalysis