Mpemba Index and Anomalous Relaxation

Abstract

The Mpemba effect is a counterintuitive relaxation phenomenon, where a system prepared at a hot temperature cools down faster than an identical system initiated at a cold temperature when both are quenched to an even colder bath. Such nonmonotonic relaxations are observed in various systems, including water, magnetic alloys, polymers, and driven granular gases. We analyze the Mpemba effect in Markovian dynamics and discover that a stronger version of the effect often exists for a carefully chosen set of initial temperatures. In this strong Mpemba effect, the relaxation time jumps to a smaller value leading to exponentially faster equilibration dynamics. The number of such special initial temperatures defines the Mpemba index, whose parity is a topological property of the system. To demonstrate these concepts, we first analyze the different types of Mpemba relaxations in the mean-field antiferromagnetic Ising model, which demonstrates a surprisingly rich Mpemba-phase diagram. Moreover, we show that the strong effect survives the thermodynamic limit and that it is tightly connected with thermal overshoot; in the relaxation process, the temperature of the relaxing system can decay nonmonotonically as a function of time. Using the parity of the Mpemba index, we then study the occurrence of the strong Mpemba effect in a large class of thermal quench processes and show that it happens with nonzero probability even in the thermodynamic limit. This study is done by introducing the isotropic model for which we obtain analytical lower bound estimates for the probability of the strong Mpemba effects. Consequently, we expect that such exponentially faster relaxations can be observed experimentally in a wide variety of systems.