Experimental study of low-temperature combustion performance in hydrogen/air mixtures over Pt–Cu/HZSM-5/cordierite bimetallic catalysts

Abstract

Catalytic combustion provides a feasible technology to effectively avoid NOx formation due to the high temperature in the process of hydrogen combustion. Recently, the development of efficient and affordable catalysts has attracted extensive attention as the cost of noble metals remained high. In this study, a list of cordierite monolithic catalysts with low noble metal loading are prepared by introducing the appropriate amount of transition metals (Mn, Cu, Fe, Co, and Ce), and their catalytic performance are further investigated. On this basis, the study on catalytic stability and kinetic is carried out, and the synergistic interaction between the bimetals is revealed with comprehensive characterization methods. The results show that Cu could promote the reaction rate of the Pt-based catalyst which show the best catalytic performance with the Cu loading of 1 g/L. The ignition temperature T10 is 58.5 °C, and the burnout temperature T100 is 100 °C, with activation energy as low as 44.00 kJ/mol. The enhancement of the catalytic performance is attributed to the interaction between the bimetallic elements. On the one hand, the valence state of Cu and Pt is changed, and on the other hand the dispersion of Pt get improved, which contributed to the catalytic reaction rate.

Keywords

• Catalytic combustion
• Pt-based catalysts
• Non-noble metal decoration
• Bimetal interaction