Acta Crystallographica Section E: Crystallographic Communications (Jul 2019)

Crystal structure of N-(diphenylphosphoryl)-2-methoxybenzamide

  • Victor A. Trush,
  • Nataliia S. Kariaka,
  • Viktoriya V. Dyakonenko,
  • Svitlana V. Shishkina,
  • Vladimir M. Amirkhanov

DOI
https://doi.org/10.1107/S205698901900762X
Journal volume & issue
Vol. 75, no. 7
pp. 939 – 941

Abstract

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In the title compound, C20H18NO3P, the C=O and P=O groups of the carbacylamidophosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N—H group is involved in the formation of an intramolecular hydrogen bond. In the crystal, molecules do not form strong intermolecular interactions but the molecules are linked via weak C—H...π interactions, forming chains along [001].

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