Beilstein Journal of Organic Chemistry (Dec 2011)

Sexithiophenes as efficient luminescence quenchers of quantum dots

  • Christopher R. Mason,
  • Yang Li,
  • Paul O’Brien,
  • Neil J. Findlay,
  • Peter J. Skabara

DOI
https://doi.org/10.3762/bjoc.7.202
Journal volume & issue
Vol. 7, no. 1
pp. 1722 – 1731

Abstract

Read online

Sexithiophenes 1a and 1b, in which a 4-(dimethylamino)phenyl unit is incorporated as an end-capping group, were synthesised and characterised by cyclic voltammetry, absorption spectroscopy and UV–vis spectroelectrochemistry. Additionally, their ability to function as effective luminescence quenchers for quantum dot emission was studied by photoluminescence spectroscopy and compared with the performance of alkyl end-capped sexithiophenes 2a and 2b.

Keywords