Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage

Suya Cui; Xiaoyun Wu; Wei Ma; Weijun Tang; Huaming Sun; Jianliang Xiao; Dong Xue; Chao Wang

Green Synthesis and Catalysis (Aug 2021)

Synthesis of 2H-pyrroles via iron catalyzed dehydrogenative coupling and C–C bond cleavage

Suya Cui,
Xiaoyun Wu,
Wei Ma,
Weijun Tang,
Huaming Sun,
Jianliang Xiao,
Dong Xue,
Chao Wang

Affiliations

Suya Cui: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
Xiaoyun Wu: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
Wei Ma: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
Weijun Tang: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
Huaming Sun: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
Jianliang Xiao: Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, United Kingdom
Dong Xue: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China; Corresponding authors.
Chao Wang: Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China; Corresponding authors.

Journal volume & issue: Vol. 2, no. 3
pp. 307 – 310

Abstract

Read online

Iron catalyzed coupling of β-amino alcohols with allylic alcohols for the synthesis of 3,4-dihydro-2H-pyrrole derivatives has been developed. Mechanistic studies suggest that the reaction involves iron catalyzed dehydrogenative coupling and C–C bond cleavage processes.

Published in Green Synthesis and Catalysis

ISSN: 2666-5549 (Online)
Publisher: KeAi Communications Co. Ltd.
Country of publisher: China
LCC subjects: Technology: Chemical technology; Science: Chemistry: Organic chemistry: Biochemistry
Website: https://www.keaipublishing.com/en/journals/green-synthesis-and-catalysis/

About the journal

Abstract

Keywords