Direct Preparation of Cellulose Nanofibers from Bamboo by Nitric Acid and Hydrogen Peroxide Enables Fibrillation via a Cooperative Mechanism

Abstract

Separating the fibers, deconstructing both the interlamellar structures and the intermicrofibrils structures in the cell wall, and cleaving the amorphous regions of cellulose (all reached in one bath chemical-assisted treatment), then extracting cellulose nanofibers (CNFs) from biomass, is both challenging and imperative. A simple, cost-effective and green strategy for extracting CNFs from bamboo using nitric acid and hydrogen peroxide (NCHP), to enable fibrillation via a cooperative mechanism, is demonstrated herein. NCHP-CNFs 13.1 ± 2.0 nm wide, with a high aspect ratio, 74% crystallinity, excellent UV resistance and high thermal stability, were successfully extracted by treatment in HNO3 aqueous solution, at a concentration of 3.2 mol/L, and treatment with 60.00 mmol/g H2O2 at 50 °C for 48 h. The yields of NCHP-CNFs reached 73% and 99% based on biomass and cellulose, respectively, due to the high delignification selectivity of OH+ and the mild aqueous conditions during the NCHP treatment. These NCHP-CNFs with excellent UV resistance can potentially be applied in the field of UV-resistant coatings, to replace organic and inorganic materials.

Keywords

• cellulose nanofibers
• biomass
• nitric acid
• hydrogen peroxide