Microspheres from light—a sustainable materials platform

Abstract

Photopolymerization provides a safe and mild fabrication pathway towards polymeric particles but the implementation of photochemistry from solution to dispersed media to produce particles is far from trivial. Here, the authors demonstrate an additive-free step-growth photopolymerization with sunlight, exploiting the photoinduced Diels-Alder to fabricate micrometer sized polymeric particles.