Luminescent Schiff-Base Lanthanide Single-Molecule Magnets: The Association Between Optical and Magnetic Properties

Abstract

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Luminescent Single-Molecule Magnets (SMM) belong to a new class of multifunctional molecule-materials that associate luminescence and slow relaxation of their magnetization within a single crystalline phase. We present in this mini-review the major advances that have been achieved in this new field over the last few years. More particularly, we will focus on the use of Schiff-base complexes in order to correlate magnetism and luminescence, as well as discussing the future outlooks of the field.

Keywords

• lanthanides
• single-molecule magnet
• multifunctional molecular materials
• luminescence
• anisotropy
• crystal-field splitting