Sustainable Alternatives to Cement: Synthesizing Metakaolin-Based Geopolymer Concrete Using Nano-Silica

Abstract

The emission of carbon dioxide gas from the cement manufacturing industry has raised concerns about global warming. Geopolymer concrete (GC) is gaining attention as a sustainable and environmentally friendly alternative to traditional cement concrete. The current study focused on using local clay to synthesize and characterize metakaolin-based GC with varying percentages of nanosilica (NS) (1.5%, 3.0%, 4.5%, 6.0%, and 7.5% by weight of MK content) using NaOH/sodium silicate. The geopolymer specimens were cured at room temperature for 28 days, and their workability, compressive, tensile, and flexural strengths were measured to evaluate the influence of NS on the concrete’s mechanical properties. The study found that the compressive, tensile, and flexural strengths of the GC increased gradually up to 6.0% NS, but any further increase in its ratio resulted in a reduction in mechanical characteristics. The study concludes that the addition of 6.0% NS in metakaolin (MK)-based GC produces the highest mechanical properties, improving the compressive strength of the GC mix by 34.3% compared to the control GC mix and improving the flexural and split tensile strengths by 39% and 37%, respectively, compared to control GC strengths. Furthermore, the statistical analysis confirms nano-silica’s significant impact on geopolymer concrete’s mechanical properties, emphasizing its role in improving performance and sustainability as an alternative to cement-based materials.

Keywords

• nano-silica
• metakaolin
• geopolymer concrete
• ambient curing
• strength properties
• mechanical properties