Nature Communications (Jan 2018)

Fused electron deficient semiconducting polymers for air stable electron transport

  • Ada Onwubiko,
  • Wan Yue,
  • Cameron Jellett,
  • Mingfei Xiao,
  • Hung-Yang Chen,
  • Mahesh Kumar Ravva,
  • David A. Hanifi,
  • Astrid-Caroline Knall,
  • Balaji Purushothaman,
  • Mark Nikolka,
  • Jean-Charles Flores,
  • Alberto Salleo,
  • Jean-Luc Bredas,
  • Henning Sirringhaus,
  • Pascal Hayoz,
  • Iain McCulloch

DOI
https://doi.org/10.1038/s41467-018-02852-6
Journal volume & issue
Vol. 9, no. 1
pp. 1 – 9

Abstract

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Semiconducting polymers are usually prepared by transition metal mediated coupling reactions that cause problems for sustainability and biological applications. Here the authors synthesise fused electron deficient polymers that are air stable and have high electron affinities, via metal free aldol polymerisation reactions.