Efficient degradation of bisphenol A and amino black 10B by magnetic composite Fe3O4@MOF-74 as catalyst

Abstract

Metal-organic frameworks (MOFs) exhibit high chemical stability and porosity, and have been widely applied in various fields including selective adsorption and separation, sensors, and catalysis. When combined with Fe3O4, they effectively address issues such as aggregation of Fe3O4 particles and the difficulty in recovering MOFs as catalysts. Therefore, in this study, we used a simple solvothermal method as a catalyst to synthesize a high specific surface area magnetic composite Fe3O4@MOF-74, which was used to catalyze the degradation of bisphenol A (BPA) and amino black 10B in wastewater. We activated Na2S2O8 to generate radicals for oxidizing and degrading BPA and amino black 10B. Experimental results showed that at 35 °C, with Fe3O4@MOF-74 (Fe3O4: MOF-74=1:1) concentration of 0.2 g/L and Na2S2O8 concentration of 2 g/L, the catalytic effect is efficient and economical. Meanwhile, removal rates of BPA and amino black 10B exceeded 95.58 % over a broad pH range (pH 3–9). Furthermore, even after multiple cycles of use, Fe3O4@MOF-74 maintained catalytic degradation rates of BPA and amino black 10B above 93.24 % and 95.01 %, respectively. Additionally, in water samples, removal rates of BPA and amino black 10B exceeded 91.55 %. This study provides a new and efficient catalyst material for wastewater treatment, which is expected to play an important role in environmental remediation.

Keywords

• MOFs
• Catalyst
• Degradation
• Amino black 10B
• Bisphenol A