Nature Communications (Apr 2018)

Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation

  • Liang Wang,
  • Erjia Guan,
  • Jian Zhang,
  • Junhao Yang,
  • Yihan Zhu,
  • Yu Han,
  • Ming Yang,
  • Cheng Cen,
  • Gang Fu,
  • Bruce C. Gates,
  • Feng-Shou Xiao

DOI
https://doi.org/10.1038/s41467-018-03810-y
Journal volume & issue
Vol. 9, no. 1
pp. 1 – 8

Abstract

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Understanding of the structures and roles of catalyst promoters markedly lags behind the understanding of the structures and roles of catalytic sites. Here, the authors address this challenge by incorporating a single-site promoter—tin—on a TiO2 surface to enhance the catalytic activity of various metals on the TiO2 in selective hydrogenation of nitroarenes.