Journal of the Serbian Chemical Society (Jan 2016)

Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives

  • Stojković Danijela Lj.,
  • Bacchi Alessia,
  • Capucci Davide,
  • Milenković Milica R.,
  • Čobeljić Božidar,
  • Trifunović Srećko R.,
  • Anđelković Katarina,
  • Jevtić Verica V.,
  • Vuković Nenad,
  • Vukić Milena,
  • Sladić Dušan

DOI
https://doi.org/10.2298/JSC160915087S
Journal volume & issue
Vol. 81, no. 12
pp. 1383 – 1392

Abstract

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A Pd(II) complex with methyl 2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetate was synthesized. The structures of both the ligand and Pd(II) complex were determined by elemental analysis, IR and NMR spectroscopy. Recrystallization of Pd(II) complex from DMF/water solution resulted in its hydrolysis and formation of dimethylamine-(2-((1-(2,4-dioxochroman-3-ylidene)ethyl)amino)acetato)palladium(II) complex, the structure of which was determined by elemental analysis, IR, 1H and 13C NMR spectroscopy, as well as X-ray analysis. [Projekat Ministarstva nauke Republike Srbije, br. OI 172055 i br. OI 172016]

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