Acta Crystallographica Section E (Oct 2011)

Dichlorido[1-(2,6-dimethylphenylimino)-1,2-diphenylpropan-2-ol-κ2N,O]palladium(II) methanol monosolvate

  • Hua-Gang Yao,
  • Dong-Sheng Shen,
  • Ying-Tang Huang,
  • Feng-Shou Liu

DOI
https://doi.org/10.1107/S1600536811037986
Journal volume & issue
Vol. 67, no. 10
pp. m1435 – m1435

Abstract

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The title compound, [PdCl2(C23H23NO)]·CH3OH, was obtained by the reaction of 1-(2,6-dimethylphenylimino)-1,2-diphenylpropan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hydroxylimine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex molecule and the uncoordinated methanol molecule are connected via an O—H...O hydrogen bond.