Blocking Hydrogen Diffusion in Palladium Cathode i—<i>Analyzed by Electrochemistry</i>; ii—<i>Analyzed by Chaos</i>

Abstract

Electrochemical chaos is caused when, during diffusion, hydrogen and, at worst, tritium is trapped in palladium after the formation of adsorbates. The mechanism leads to cracking corrosion, as seen by scanning electron microscopy. The instabilities were apprehended from voltammetry and electrochemical impedance spectroscopy in the active potential where the cathodic hydrogen is charged from two models of transients. Tests performed using an electrochemical chaos analyzer simplify the expertise of the palladium cathode in focusing on the blocking diffusion of hydrogen. A complex electrical circuit of chaos is considered for adsorption and the blocking diffusion. Depending on the active potential, distinct behavior such as the transformation of transients and limited diffusion can occur. Phase-space spectra are obtained, and synchronization has been developed to clarify the chaos leading to the cracking of palladium. By applying these different analytical tests for the restricted diffusion, it is possible to interpret the processes from the power spectra, autocorrelation function, or the divergence coefficient in the region of active potentials. Analyzers can detect flaws in this hydrogen diffusion process and suggest corrective measures.

Keywords

• hydrogen
• palladium
• blocking diffusion
• cathode
• chaos analysis